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During the bioleaching process, microbes generate energy by oxidising sulfur and iron from sulfide minerals. First, acquisition of iron by microorganisms for biochemical requirements is a key process in the iron cycle in oxygenated, circumneutral ph environments, where the solubility of fe (iii) (oxyhydr)oxides is extremely low. Iron metabolism in microbes involves the acquisition, storage, and regulation of iron

Iron reduction occurs through two major mechanisms Microbes are intimately involved in the iron cycle Abiotic (chemical) reduction and biotic (microbial) reduction

[1][3] among these, biologically processes are particularly significant in natural environments and are increasingly leveraged in sustainable technologies for metal recovery and environmental remediation.

In this topic, we have gathered contributions from scientists working in diverse disciplines with common interests in iron cycling at the process and gene levels from the archaea, bacteria, and fungi. Light is the driving force of the fe cycle in the natural environment because of its ability to act as an energy source for microbial metabolism while participating in numerous abiotic and biological fe cycling process (lueder et al., 2020a).

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